According to TMZ, the divorce was filed last week but it is unclear who chose to end the marriage.
They have two young children together, son Maceo, aged one, and daughter Sadie, who is three.
Jesse and Aryn married in September of 2012, but were together long before his acting career took off.
They have not been photographed together since January of 2016 and there is no sign of Aryn on Jesse's Instagram page within the last two years.
The 35-year-old star and activist made headlines in 2016 with a politically charged speech at the BET Awards in Los Angeles.
During the speech, he thanked his 'amazing wife who changed his life.'